in neat (no solvent) react. at 80-100 °C or 70-80 °C; formation of a mixt. of PSFCl2 and PSF2Cl;;
参考文献
Delwaulle, M.-L.; Francois, F.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1947 , vol. 225, p. 1308 - 1309
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Gmelin Handbook: P: MVol.C, 263, page 602 - 605
in neat (no solvent) at about 60°C under pressure; further products;; condensation; removal of SiF4 by fractional sublimation; isolation by distillation with pressure;;
参考文献
Booth, H. S.; Osten, R. A.
Journal of the American Chemical Society, 1945 , vol. 67, p. 1092 - 1096
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Gmelin Handbook: Si: MVol.B, 264, page 713 - 715
antimony pentachloride in not given fluorination of PSCl3 with SbF3; addn. of SBF3 at 70-80 °C; ratio of products depending on pressure and temp.;; fractional distn., cooling agent liquid air or CO2-acetone;;
参考文献
Industrial and Engineering Chemistry, , vol. 29, p. 470 - 475
