in neat (no solvent) byproducts: SiF4, F3SiOSiF3; degassing of SbF3 and freezing (liq. N2), condensing of Si2Cl6 on surface of SbF3, warming to room temp. (shaking), react. time at room temp. is 15 min); sepn. by 3-trap distn. at -78, -131 (product) and -196°C; IR andmass spectroscopy (SiF4 and F3SiOSiF3 impurities);
参考文献
Bains, Swroop K.; Noble, Paul N.; Walsh, Robin
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1986 , vol. 82, p. 837 - 848
in toluene under N2 or Ar; SbF3 and toluene stirred at -78°C; soln. of (HNBCl)3 in toluene added dropwise; warmed to ambient temp.; filtered; filtrate stored at -25°C for 1 d;
参考文献
Anand, Benadir; Noeth, Heinrich; Schwenk-Kircher, Holger; Troll, Alexander
European Journal of Inorganic Chemistry, 2008 , # 20 p. 3186 - 3199
in neat (no solvent) at about 60°C under pressure; further products;; condensation; removal of SiF4 by fractional sublimation; isolation by distillation with pressure;;
参考文献
Booth, H. S.; Osten, R. A.
Journal of the American Chemical Society, 1945 , vol. 67, p. 1092 - 1096
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Gmelin Handbook: Si: MVol.B, 264, page 713 - 715
