antimony pentachloride in neat (no solvent)
byproducts: H2; conversion of 2.093g SiHCl3 with 0.5g SbF3 in presence of 0.2ml SbCl5 at 10-15 °C for a period of 3 hours;;
参考文献
Emeleus, H. J.; Maddock, A. G.
Journal of the Chemical Society, 1944 , p. 293 - 296
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Gmelin Handbook: Si: MVol.B, 233, page 635 - 638
in not given
SbF3 was dropped into liquid SiHCl3 containing SbCl5; Purification by trap to trap distillation;
参考文献
Arthur, Neville L.; Potzinger, Peter; Reimann, Bruno; Steenbergen, H. Peter
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1989 , vol. 85, p. 1447 - 1464
in neat (no solvent)
addn. of 80 g SbF3 to a mixt. of 200 g POCl3 and 50 g SbCl5 at 75 °C and 190-200 Torr;; products contains 55 percent PF3, 5 percent POF2Cl and 40 percent POFCl2;;
参考文献
Booth, H. S.; Dutton, F. B.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2937 - 2940
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Gmelin Handbook: P: MVol.C, 212, page 487 - 489
in acetonitrile
fluoride to P molar ratio from 1:1 to 2:1, a soln. of P compd. frozen inliq. N2, ftoride added, gradually heated, or reacted at room temp.; soln. separated, not isolated, detected by NMR;
参考文献
Kokunov; Ershova; Razgonyaeva
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2002 , vol. 28, # 7 p. 461 - 463
in neat (no solvent)
addn. of 175 g powdered SbF3 to a mixt. of 130 g PCl3 and 2 g PCl5 (catalyst) in a round bottom flask with reflux condenser; keeping temp. of the vessel at 40 °C; sampling PFCl2 in a gas trap (liquid O2);;
dry air atmosphere; heating (200-300°C, 2-25 h, autoclave);
参考文献
Popov, A. I.; Scharabarin, A. V.; Sukhoverkhov, V. F.; Tchumaevsky, N. A.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1989 , vol. 576, p. 242 - 254
