in neat (no solvent) slight excess over the stoich. amt. of COF2 required; reaction mixt. heated in a stainless steel or monel cylinder at 210°C for 46 h;
参考文献
Mallela, S. P.; Gupta, O. D.; Shreeve, Jean'ne M.
Inorganic Chemistry, 1988 , vol. 27, p. 208 - 209
dihydrogen hexachloroplatinate in water byproducts: Pt; In presence of H2PtCl6 complete reaction at ambient temp. within a few minutes; H2PtCl6 is reduced to form Pt;;
参考文献
Schaefer, H.; Kahlenberg, F.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1958 , vol. 294, p. 242 - 253
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Gmelin Handbook: Ta: MVol.A2, 68, page 535 - 537
in melt placing of mixt. of Ta with SnF2 (molar ratio SnF2:Ta=1.46) in Fluoroplast-4 ampule, closing by screwed stopper, exposition for 1.00 h at 240°C; various product ratio yields for various conditions; cooling, stirring up in water, collection, drying;
参考文献
Goryacheva; Rakov; Solov'ev
Russian Journal of Inorganic Chemistry, 2001 , vol. 46, # 7 p. 949 - 952
