in neat (no solvent)
byproducts: SiF4, Cl2; High Pressure; heating at 70°C for 20 d in a Monel Parr bomb, then reheating at 110°C for 2 mo; then the mixt. of products was heated at 180°C for 20 d;; detected by IR-expt.;
参考文献
Lawlor, Lawrence J.; Passmore, Jack
Canadian Journal of Chemistry, 1984 , vol. 62, p. 1477 - 1482
in neat (no solvent)
WTe2 placed in a tungsten saucer, addn. of a small amt. of sulfur as fuse, react. with fluorine in a prefluorinated perforated nickel crucible;
参考文献
O'Hare, P. A. G.; Hope, G. A.
Journal of Chemical Thermodynamics, 1992 , vol. 24, # 6 p. 639 - 647
→
反应条件
in neat (no solvent)
thermal treatment of RbTeF5 in air, 450°C, 3h;
参考文献
Germain, Patrick; Claudy, Pierre; Letoffe, Jean-Marie; Bastide, Jean-Pierre
Materials Research Bulletin, 1988 , vol. 23, p. 1731 - 1738
in neat (no solvent)
High Pressure; TeFCl5 (5.81 mmol) was allowed to react with F2 (23.2 mmol) for 3 d at 165°C in a Parr bomb;; detected by IR-, Raman and NMR-expt.;
参考文献
Lawlor, Lawrence J.; Passmore, Jack
Canadian Journal of Chemistry, 1984 , vol. 62, p. 1477 - 1482
in neat (no solvent)
heat sealing of the NMR tube with Xe-compound; cooling to -196°C; addn. of SbF5 via syringe; removing tube from drybox while cold- and heat sealing under a dynamic vac. at -196°C; not isolated; detection of compounds at 5°C by NMR;
参考文献
Syvret, Robert G.; Mitchell, Kenneth M.; Sanders, Jeremy C. P.; Schrobilgen, Gary J.
Inorganic Chemistry, 1992 , vol. 31, p. 3381 - 3385
in neat (no solvent)
further products; heat sealing of the NMR tube with Xe-compound; cooling to -196°C; addn. of SbF5 via syringe; removing tube from drybox while cold- and heat sealing under a dynamic vac. at -196°C; not isolated; detection of compounds at 5°C by NMR;
参考文献
Syvret, Robert G.; Mitchell, Kenneth M.; Sanders, Jeremy C. P.; Schrobilgen, Gary J.
Inorganic Chemistry, 1992 , vol. 31, p. 3381 - 3385
