in solid matrix byproducts: TiF; Irradiation (UV/VIS); reaction of titanium ablated atoms with arsenic trifluoride in Ar with condensation at 5 K for 60 min, irradiation at 290 mn for 20 min, irradiation at >220 nm for 20 min; IR monitoring;
参考文献
Wang, Xuefeng; Lyon, Jonathan T.; Andrews, Lester
Inorganic Chemistry, 2009 , vol. 48, # 13 p. 6297 - 6302
in sulfur dioxide
1 d; slow removal of solvent, cooling to 0°C;
参考文献
Brownridge, Scott; Cameron, T. Stanley; Passmore, Jack; Schatte, Gabriele; Way, Todd C.
Journal of the Chemical Society - Dalton Transactions, 1996 , # 12 p. 2553 - 2570
in not given
byproducts: H2O; reaction of HF with AsCl3 in quartz-vessels;;
参考文献
Kwasnik, W.
W. Klemm in FIAT Review, Naturforschung und Medizin in Deutschland 1939-1946, fuer Deutschland bestimmte Ausgabe der FIAT Review ofGerman Science, Dieterichsche Verlagsbuchhandlung, Wiesbaden, Bd. 23, S. 275
bromine
Condensing of AsF5 onto Br2 and AsBr3 at -196°C, warming to -5°C until a clear soln. is formed (1 min), cooling (-196°C), repeating of process in excess of 10 times.; Evapn. of volatiles in vac (-5°C, 10 min).;
参考文献
Klapoetke, Thomas; Passmore, Jack
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1990 , # 12 p. 3815 - 3822
NaF in sulfur dioxide
AsF5 is condensed to a frozen soln. of Cp2VCl2 and NaF in SO2 at -196°C, warming up, stirring at room temp. for 12 h, removal of SO2 and AsF3 in vac.; residue is recrystd. from SO2; elem. anal.;
参考文献
Gowik, Petra; Klapoetke, Thomas M.; Siems, Karsten; Thewalt, Ulf
Journal of Organometallic Chemistry, 1992 , vol. 431, # 1 p. 47 - 53
→
反应条件
HF in sulfur dioxide
react. of vanadocene with AsF5 (excess) in the presence of an equimolar amt. of HF in SO2;
参考文献
Gowik, Petra; Klapoetke, Thomas M.; Siems, Karsten; Thewalt, Ulf
Journal of Organometallic Chemistry, 1992 , vol. 431, # 1 p. 47 - 53
