反应条件
1: MeONa / methanol / 0.5 h / Ambient temperature
2: 98 percent / periodic acid dihydrate / diethyl ether; tetrahydrofuran / 0.5 h / Ambient temperature
3: LiAlH4 / diethyl ether / 2 h
4: H2 / Adams' platinum oxide / methanol
5: 63.7 percent / pyridinium chlorochromate, sodium acetate / CH2Cl2 / 1 h / Ambient temperature
6: 27.3 percent / n-BuLi / hexane; tetrahydrofuran / 1.) -20 deg C, 1 h, 2.) -20 deg C, 1 h; r.t., 1 h
7: 58.1 percent / H2 / palladium-charcoal / ethanol; hexane
View Scheme
参考文献
Hoshino, Chimaki; Mori, Kenji
Agricultural and Biological Chemistry, 1980 , vol. 44, # 12 p. 3007 - 3010