hydrogen in neat (no solvent) formation of Bi and evolution of BiCl3 vapor on heating in H2 stream;;
参考文献
Annalen der Physik (Weinheim, Germany), , vol. 110, p. 428 - 428
→
反应条件
in ethanol High Pressure; mixing Bi2S3 and CuCl in ethanol, heating at 120°C for 2 d in autoclave, cooling to room temp.; filtration, washing with dild. HCl, water, ammonia, ethanol, drying in vac.;
参考文献
Li, Zhengquan; Yang, Huan; Ding, Yue; Xiong, Yujie; Xie, Yi
Dalton Transactions, 2006 , # 1 p. 149 - 151
in tetrachloromethane under N2; mixt. of WCl6 (3.26 mmol), CCl4 (1.63 mmol) and Bi (4.35 mmol)heated in evacuated and sealed Pyrex ampule in tube furnace at 400.degr ee.C for 3 days; sublimation of BiCl3 at 360°C;
参考文献
Journal of the American Chemical Society, , vol. 125, # 38 p. 11464 - 11465
mercury dichloride in chloroform byproducts: C6H6; 5h heating to reflux on steam bath with stirring;; (C6H5)2Hg extracted from precipitate with ether, C6H5HgCl with benzene and BiCl3 with acetone;;
参考文献
Tr. Tashkentsk. Farmatsevt. Inst., , vol. 1, p. 321 - 323
C. A., , p. 15389
