in neat (no solvent, solid phase) CuI and HgBrI (molar ratio 4:1, 3:1 and 1:2) mixed, heated in air at 120°C for 48 h, cooled to 30°C; analysed by X-ray diffraction;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 55, # 11 p. 3607 - 3611
in solid byproducts: HgCl2; mixing HgClBr and CuI (molar ratio of 1:1) in an agate mortar, heating at 80°C for 3 days; mechanism discussed;; cooling to room temp., not isolated, detected by X-ray diffraction;
参考文献
Journal of Solid State Chemistry, , vol. 105, p. 130 - 135
in solid byproducts: HgCl2; mixing HgClBr and CuI (molar ratio of 1:2) in an agate mortar, heating at 80°C for 3 days; mechanism discussed;; cooling to room temp., not isolated, detected by X-ray diffraction;
参考文献
Journal of Solid State Chemistry, , vol. 105, p. 130 - 135
in neat (no solvent, solid phase) CuI and HgBr2 (molar ratio 1:1 and 1:2) mixed, maintained in air at 30°C for 48 h or mixt. of CuI and HgBr2 ( molar ratio 3:1 and 2:1) heated in air at 120°C for 48 h, cooled to 30°C; analysed by X-ray diffraction;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 55, # 11 p. 3607 - 3611
in further solvent(s) 25°C, 0.1 M tetraethylammonium perchlorate base electrolyte in propylene carbonate, thermodynamics of CuBr2(1-) complex formation given, CuBr pptd.; potentiometric titration;
参考文献
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, , vol. 84, # 11 p. 4013 - 4022
