反应条件
(2,6-bis(diisopropylphosphinomethyl)pyridine)iridium(III)trihydride in tetrahydrofuran; water-d2
Kinetics; High Pressure; mixt. of Ir complex and soln. of KOH in D2O placed in stainless autoclave; pressurized by equimolar mixt. of CO2 and H2; heated to 200°C (oil bath); stirred for 2 h; not isolated; detd. by (2)H NMR spectra;
参考文献
Tanaka, Ryo; Yamashita, Makoto; Chung, Lung Wa; Morokuma, Keiji; Nozaki, Kyoko
Organometallics, 2011 , vol. 30, # 24 p. 6742 - 6750
