iridium Kinetics; under ultra-high vac. for partial pressures of (15)NO and D2 between 5*10**-8 and 1*10**-6 Torr, total pressures between 10**-7 and 10**-6 Torr, and surface temp. between 300 and 1000 K;
in solid matrix byproducts: (D2O)2; Irradiation (UV/VIS); Hg evapd. from liq. at 50°C; codeposited with O2 in excess D2 onto CsI window at 5 K for 30 min; irradiated (mercury arc, > 220 nm) for 42 min; monitored by IR spectra;
in gaseous matrix Kinetics; react. in a discharge flow system with MS spect. detection (O-atom generation by titration react. of N/NO), carrier gas Ar, room temp., pressure 400 Pa, coated reactor; product distribution; products not isolated, detd. by MS, GC;
参考文献
Journal of Physical Chemistry, , vol. 95, # 11 p. 4393 - 4400
