in nitrobenzene
Electrolysis; electrolysis of a mixt. of PBr5 and IBr in nitrobenzene with Pt electrodes at 240 V; pptn. of P at cathode and of I2 at anode;;
参考文献
Kuz'menko, A. A.; Fialkov, Ya. A.
Zh. obshch. Khim., 1949 , vol. 19, p. 1007 - 1013
C., 1949 , p. E 3745
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Gmelin Handbook: P: MVol.C, 232, page 531 - 533
in neat (no solvent)
melting a mixt. of 51.1 mol-percent PBr3 and 48.9 mol-percent IBr; react. of the prod. with PBr3 then with CS2;; drying the residue at 50 °C in a stream of CO2;;
参考文献
Fialkov, Ya. A.; Kuz'menko, A. A.
Zh. obshch. Khim., 1949 , vol. 19, p. 1645 - 1652
C. A., 1950 , p. 1354
Full Text Show Details
Gmelin Handbook: P: MVol.C, 232, page 531 - 533
in sulfuric acid
dry N2-atmosphere; mixing equimolar amts. in 100 percent H2SO4 (room temp.); product mixt. not sepd., detd. by (31)P-NMR spectroscopy;
参考文献
Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1591 - 1594
