in neat (no solvent) passing an equimolar mixt. of PCl3 and PBr3 through a glass tube containing porcelain pieces heated with an electric furnace; temp. of the formed gases 200 °C;;
bromine in neat (no solvent) fluorination of PBr3 with SbF3 using Br2 as catalyst;;
参考文献
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937
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Gmelin Handbook: P: MVol.C, 222, page 509 - 511
in neat (no solvent) passing gaseous PBr3 over CaF2, heated to 200°C;;
参考文献
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937
Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 222, page 509 - 511
in neat (no solvent) fluorination with CaF2 at 200°C;;
参考文献
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937
Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 216, page 496 - 498
in neat (no solvent) byproducts: PF3, (C2H5)2NPBr2; exclusion of moisture, mixt. heated to 70-75°C with stirring for2 h, N2 stream maintained during react.; fractionated (-90, -135 and -196°C), BrPF2 collected in the -135°C trap;
参考文献
Albers, W.; Krueger, W.; Storzer, W.; Schmutzler, R.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1985 , vol. 15, p. 187 - 196
