in diethyl ether reaction of SeF4 with a solution of BiBr3 (10 percent) in ether with precipitation of BiF3 and formation of an orange yellow solution of SeBr4 in ether;;
参考文献
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 244, p. 1779 - 1782
Schneider, R.
Annalen der Physik (Weinheim, Germany), 1866 , vol. 129, p. 459 - 459
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Schneider, R.
Z. Chemie (2), 1867 , vol. 3, p. 25 - 25
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Gmelin Handbook: Se: MVol.B, 68, page 148 - 150
in neat (no solvent) mixture of 1 mol CBr4 and 4 mol Se; in a closed vessel at 250°C 20h;; distillation of Se2Br2 and small amount of CBr4, solid compound SeBr4, residue in flask: grey Se;;
in neat (no solvent, solid phase) heated at 100°C; subjected to a dynamic vac. for 3 h, volatile product was collected at -196°C, SeBr4 and SeBr3AsF6 were identified by Raman Spectra;
参考文献
Canadian Journal of Chemistry, , vol. 65, p. 1584 - 1593
