pyridine hydrochloride in chloroform to the soln. of SiBr4/CHCl3 the soln. of pyridinium chloride/CHCl3 was added dropwise with stirring, stirred at 298°C under protective gas; gas chromy.;
参考文献
Hass, D.; Bechstein, O.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1981 , vol. 483, p. 140 - 144
in gas High Pressure; reagents added to tube in dry ice bath, sealed in amts. to develop about 30-50 atm of pressure at 300°C, heated at 310-350°C for 1.5-69 h; analyzed by GLC;
参考文献
Scaduto, Patricia M.; Speier, John L.
Inorganic Chemistry, 1983 , vol. 22, p. 3363 - 3364
in neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 0.25 h; not isolated; IR spectroscopy (identified 20percent SiBr3H and 20percent SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent) addn. of SbF3 to a boiling soln. of Br2 free SiBr4 under stirring;; distillation;;
参考文献
Schumb, W. C.; Anderson, H. C.
Journal of the American Chemical Society, 1936 , vol. 58, p. 994 - 996
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Gmelin Handbook: Si: MVol.B, 271, page 730 - 732
in neat (no solvent) byproducts: SiBr4; distillation of a solution of I2 and SiBr4 or passing the mixture in a H2 stream to crystalline Si near red heat;;
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Besson, A.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 112, p. 1447 - 1449
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Gmelin Handbook: Si: MVol.B, 275, page 742 - 743
in neat (no solvent) under inert atmosphere; eqimolar amt. of SiCl4 and SiBr4 equilibrated by stirring at room temp. for 3 d; sepd. by repeated fractional distn. at ambient pressure; immediately frozen; characterized by (29)Si NMR;
参考文献
Hcnsen, Karl; Mayr-Stein, Ralf; Stumpf, Thorsten; Pickel, Peter; Boite, Michael; Fleischer, Holger
Journal of the Chemical Society, Dalton Transactions, 2000 , # 4 p. 473 - 477
