in neat (no solvent) byproducts: calcium silicide; reaction by leading SiCl4-vapour over an excess of heated CaH2-powder under red heat;; H2, HCl and few SiHCl3 als gasious products, CaCl2 and Ca-silicide as solid products;;
参考文献
Gmelin Handbook: Ca: MVol.B2, 6, page 275 - 277
Full Text Show Details
Besson, A.; Fournier, L.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909 , vol. 148, p. 555 - 557
in neat (no solvent) reaction by leading an excess of SiCl4-vapour over heated CaH2-powder above red heat;; H2, HCl and few SiHCl3 als gasious products, CaCl2 and amorpheous Si as solid products;;
参考文献
Gmelin Handbook: Ca: MVol.B2, 6, page 275 - 277
Full Text Show Details
Besson, A.; Fournier, L.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909 , vol. 148, p. 555 - 557
in neat (no solvent) byproducts: CaO; react. in an autoclave under H2-pressure, 300-600°C, exothermic react. (formation of CaH2 from CaCl2 and H2 during the react. possible); addn. of SiO2 for absorption of CaO;;
参考文献
Gmelin Handbook: Na: SVol.1, 61, page 259 - 261
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Farbenfabriken Bayer A.-G.
Patent: DE1036222 , 1958 ;
C., 1960 , p. 5610
