in neat (no solvent)
distillation of O2F2 into boron silicate glass in vacuum; cooling at 90°K; addn. of equimolar amount ClF at 119 - 140°K; cooling at 90°K; evacuation of F2 and Cl2;;
参考文献
Streng, A. G.; Grosse, A. V.
Advances in Chemistry Series, 1962 , vol. 36, p. 159 - 165
Show Details
Gmelin Handbook: Cl: SVol.B2, 124, page 578 - 579
in neat (no solvent)
byproducts: NaF; mixt. of NaNO3 (excess) and ClF in a stainless steel cylinder allowed to warm slowly in a dry-ice-liquid N2 slush bath from -196°VC to -78 and then toward 0°C, recooled to -196°C; fractional condensation;
参考文献
Christe, Karl O.; Wilson, William W.; Wilson, Richard D.
Inorganic Chemistry, 1989 , vol. 28, p. 675 - 677
in neat (no solvent)
byproducts: Cl2, NaF; finely powdered NaNO3 loaded into a stainless steeel cylinder, ClF (excess) added at -196°C, cylinder allowed to warm slowly to room temp., kept for 3d, cooled to -196°C; fractional condensation;
参考文献
Christe, Karl O.; Wilson, William W.; Wilson, Richard D.
Inorganic Chemistry, 1989 , vol. 28, p. 675 - 677
