cesium fluoride in neat (no solvent)
equimolar amts. of reactants in the presence of CsF; cooling to -196°C (removal of non-condensable substances), fractional condensation; product trapping at -196°C;
参考文献
Hinds, K.; Holloway, J. H.; Legon, A. C.
Chemical Physics Letters, 1995 , vol. 242, p. 407 - 414
Gmelin Handbook: Cl: SVol.B2, 115, page 564 - 565
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Rogers, M. T.; Sternberg, J. C.; Phelps, J. P.
C. A., U. S. At. Energy Comm. AECU-3928 (1956) 1/156 1960 , p. 23637
Gmelin Handbook: Cl: SVol.B2, 115, page 564 - 565
Show Details
Wendolkowski, W. S.; Davis, W.
C. A., U. S. At. Energy Comm. K-1027 (1953) 3/21 1960 , p. 23661
Stein, L.; Vogel, R. C.
Industrial and Engineering Chemistry, 1956 , vol. 48, p. 418 - 421
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Stein, L.; Vogel, R. C.
N.S.A., ANL-5441 (1955) 1/20 1955 , vol. 9, p. 6868
in neat (no solvent)
byproducts: NaF, O2; finely powdered NaNO3 loaded into a stainless steeel cylinder, ClF (excess) added at -196°C, cylinder allowed to warm slowly to room temp., kept for 10d, cooled to -196°C; fractional condensation;
参考文献
Christe, Karl O.; Wilson, William W.; Wilson, Richard D.
Inorganic Chemistry, 1989 , vol. 28, p. 675 - 677
