O2; CuCl2 in neat (no solvent) Kinetics; byproducts: H2O, HCl; the alcohol was loaded together with CuCl2 into the reactor and purged with an Ar-O2 mixture; then Cu3P was added and the mixt. reacted at 293 K, 323 K or 343 K;;
参考文献
Dorfman, Ya. A.; Petrova, T. V.; Savel'eva, L. D.
Kinetics and Catalysis, 1992 , vol. 33, p. 243 - 251
Kinetika i Kataliz, 1992 , vol. 33, p. 304 - 313
Linnemann
Justus Liebigs Annalen der Chemie, 1872 , vol. 162, p. 24
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Freund
Journal fuer Praktische Chemie (Leipzig), 1875 , vol. <2>12, p. 25,37
anhydrous phosphine; chlorine T=20°C; Ea, ΔS(excit.); var. temp.; also in the presence of pyridine; Rate constantThermodynamic data;
参考文献
Dorfman, Ya. A.; Polimbetova, G. S.; Aibasov, E. Zh.; Borangazieva, A. K.; Kokpanbaeva, A. O.; Faizova, F. Kh.
J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 10.1 p. 2256 - 2261,1860 - 1864
