carbon monoxide in n-heptane Kinetics; Addn. of Me2CHCHO to soln. of Co complex (n-heptane, CO, 25°C), stirring (1 h) until gas evolution ceased, color change from light brown to dark, further products.; GC-MS;
1: [i-PrPPh3](+)Br(-) With n-butyllithium in diethyl ether; pentane T=0 - 20°C; 10 h; 2: isobutyraldehyde in diethyl ether; pentane Wittig reaction; 24 h; Heating;
参考文献
Miller, Aubry K.; Hughes, Chambers C.; Kennedy-Smith, Joshua J.; Gradl, Stefan N.; Trauner, Dirk
Journal of the American Chemical Society, 2006 , vol. 128, # 51 p. 17057 - 17062
