diphenylditellane in benzene Irradiation (UV/VIS); nitrogen atmosphere; mercurial and PhTeTePh (2.0 equiv) in deoxygenated solvent irradiated (250-W sunlamp, 40 °C, 1h);; filtration; solvent removed (vacuum); PhCH2TePh analysed by (1)H NMR, GLC and GCMS;;
参考文献
Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.; Pla-Dalmau, Anna; Khanna, Rajive K.
Journal of the American Chemical Society, 1988 , vol. 110, # 11 p. 3530 - 3538
trans-cyclooctene in further solvent(s)
solvent was undecane and cyclooctene, under N2 or Ar, (ICH2)2Hg, HgI2 and cyclooctane were heated at 50°C for 15 min, undecane, further cyclooctene and Bz2Hg was added, heated at 85°C for 12h;
参考文献
Seyferth, Dietmar; Haas, Carol K.; Dagani, Doron
Journal of the Indian Chemical Society, 1982 , vol. 59, # 2 p. 111 - 118
diphenyl diselenide in benzene
Irradiation (UV/VIS); nitrogen atmosphere; mercurial and PhSeSePh (2.0 or 1.0 equiv) in deoxygenated solvent irradiated (250-W sunlamp, 40 °C, 5h or 6h);; filtration; solvent removed (vacuum); PhCH2CH2Ph and PhCH2SePh analysed by (1)H NMR, GLC and GCMS; various yields (PhCH2CH2Ph : PhCH2SePh = 10percent : 78percent or 40percent : 42percent) for various conditions;;
参考文献
Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.; Pla-Dalmau, Anna; Khanna, Rajive K.
Journal of the American Chemical Society, 1988 , vol. 110, # 11 p. 3530 - 3538
benzylsulfene chloride in dichloromethane
byproducts: (PhCH2)2S; addn. of Hg-compound to a soln. of organic compound cooled to -20°C;
参考文献
Nikanorov, V. A.; Rozenberg, V. I.; Gavrilova, G. A.; Reutov, O. A.
Doklady Chemistry, 1982 , vol. 262, p. 4 - 7
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 262, # 1 p. 108 - 113
