1-diethylamino-1,1-difluoro-2-chloro-2-fluoro-ethane T=130°C; 1.5 h;

1: 59.5 percent / 2-chloro-1,1,2-trifluorotriethylamine / 1.5 h / 130 °C 2: 93 percent / 10percent Pd/C, NaBH4 / methanol; H2O / 2.5 h View Scheme