in water
byproducts: water; N2 formed in concd., N2 formed in dild. soln. resp.;
参考文献
Sheppard, S. E.
Journal of the Chemical Society, 1906 , vol. 89, p. 531
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Sheppard, S. E.
Proceedings of the Chemical Society, London, 1906 , vol. 22, p. 64
sodium hydroxide in water
Kinetics; kinetic experiment in a continuous-flow stirred tank reactor: NH2OH:NaOH ratios 1.0-1.1; periodate:NH2OH ratios 2.5-3.5; iodide represents one steady state of an oscillating system; oscillatory state depends on T, ratio periodate:NH2OH and flow rate; iodide concn. detd. with an Orion iodide selective electrode and a SCE as reference, iodine concn. detd. by spectrophotometry;
参考文献
Rabai, Gyula; Epstein, Irving R.
Journal of Physical Chemistry, 1989 , vol. 93, # 22 p. 7556 - 7559
acetic acid in water
Kinetics; byproducts: H2O; NH2OH was reacted with IO3(1-) in H2O soln. in the closed reaction vessel at 25°C, pH was adjusted to 2.5 with CH3COOH, the dependence of the rate constant on NH2OH concn. was studied;
参考文献
Beck, Mihaly T.; Rabai, Gyula
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1687 - 1690
in water
byproducts: H20, NO2(1-), H(1+); product ratios depend on ratio hydroxylamine:periodate, pH is adjusted and kept constant with 0.2 M acetate buffer; iodide concn. detd. by a Orion iodide selective electrode and a SCE as reference electrode, iodine concn. detd. by spectrophotometry, nitrite concn. detd. by using Griess-Ilosovay reaction,;
参考文献
Rabai, Gyula; Epstein, Irving R.
Journal of Physical Chemistry, 1989 , vol. 93, # 22 p. 7556 - 7559
