iodine; sodium hydrogencarbonate in water
hydrolysis of PBr3 at 0°C and pH 5.7 (acetate-buffered) and oxi- dation of the obtained soln. with iodine in NaHCO3-soln. leads to hypo- phosphoric acid;; isolation in form of the Ag-salt in 55percent yield;;
参考文献
Gmelin Handbook: P: MVol.C, 67, page 142 - 144
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Blaser, B.
Ber., 1953 , vol. 86, p. 563 - 572
iodine; sodium hydrogencarbonate in water
hydrolysis of PI3 at 0°C and pH 5.7 (acetate-buffered) and oxi- dation of the obtained soln. with iodine in NaHCO3-soln. leads to hypo- phosphoric acid;; isolation in form of the Ag-salt in 37percent yield;;
参考文献
Gmelin Handbook: P: MVol.C, 67, page 142 - 144
Show Details
Blaser, B.
Ber., 1953 , vol. 86, p. 563 - 572
water; sodium hydrogencarbonate in water
oxidation of products of hydrolysis using I2 soln. at pH 5.7 in presence of buffered NaHCO3 soln.;;
参考文献
Kolitowska, J. H.
Z. Anorg. Chem., 1937 , vol. 230, p. 310 - 314
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Kolitowska, J. H.
Roczniki Chemii, 1937 , vol. 17, p. 616 - 619
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Gmelin Handbook: P: MVol.C, 215, page 494 - 496
