4,5,9,10-四氢苯芘合成路线 （共 65 条）
反应条件
in cyclohexane Irradiation;
参考文献
Journal of the American Chemical Society, , vol. 96, # 5 p. 1558 - 1564
反应条件
1: concd HCl / tetrahydrofuran; methanol 2: 95 percent / Li / tetrahydrofuran; liquid ammonia / 0.03 h / -78 °C / further reducing agent View Scheme
参考文献
Journal of Organic Chemistry, , vol. 61, # 16 p. 5481 - 5484
反应条件
1: 67 percent / KOH / benzene; ethanol 2: 93 percent / m-chloroperbenzoic acid / CHCl3 / 48 h / Ambient temperature 3: 61 percent / 500 °C / 2 - 3 Torr 4: 83.7 percent / I2 / benzene / 72 h / 60 °C 5: 80 percent / AlCl3-CH3NO2 / benzene / 2 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 15 p. 3196 - 3199
反应条件
1: 83.7 percent / I2 / benzene / 72 h / 60 °C 2: 80 percent / AlCl3-CH3NO2 / benzene / 2 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 15 p. 3196 - 3199
反应条件
1: 93 percent / m-chloroperbenzoic acid / CHCl3 / 48 h / Ambient temperature 2: 61 percent / 500 °C / 2 - 3 Torr 3: 83.7 percent / I2 / benzene / 72 h / 60 °C 4: 80 percent / AlCl3-CH3NO2 / benzene / 2 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 15 p. 3196 - 3199
反应条件
1: 61 percent / 500 °C / 2 - 3 Torr 2: 83.7 percent / I2 / benzene / 72 h / 60 °C 3: 80 percent / AlCl3-CH3NO2 / benzene / 2 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 15 p. 3196 - 3199
反应条件
hydrogen; nickel in ethanol T=250°C; P=182400 Torr; 48 h; further conditions: Raney-Nickel, 300 deg C, 250 atm, cyclohexan; Pt, 25 deg C, 1 atm, glacial AcOH; Product distribution;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 331, # 2 p. 267 - 272
反应条件
(i) aq. HCl, NaNO2, (ii) H3PO2; Multistep reaction;
参考文献
Journal of the American Chemical Society, , vol. 83, p. 1974 - 1978
反应条件
1: 57 percent / NaOMe / methanol / 3 h / Irradiation 2: 70 percent / diethyl malonate, NaOEt / ethanol / 12 h / Irradiation View Scheme
参考文献
Recueil: Journal of the Royal Netherlands Chemical Society, , vol. 102, # 4 p. 224 - 228
反应条件
1: NaOMe / methanol / Irradiation 2: 70 percent / diethyl malonate, NaOEt / ethanol / 12 h / Irradiation View Scheme
参考文献
Recueil: Journal of the Royal Netherlands Chemical Society, , vol. 102, # 4 p. 224 - 228
