tert.-butylnitrite in toluene T=110°C; 1.5 h; SolventConcentrationTemperatureTimeReagent/catalyst;

trichlorophosphate 4 h; Heating;

1: 33 percent / benzoyl chloride, AgNO3 / CH2Cl2 / 1.) 30 min, O deg C, 2.) 2 h, reflux 2: 70 percent / POCl3 / 4 h / Heating View Scheme

暂无反应条件数据

1.1: palladium 10 on activated carbon; sodium carbonate; triphenylphosphine / ethylene glycol dimethyl ether / 16 h / 80 °C / Inert atmosphere 2.1: palladium 10 on activated carbon; hydrogen / tetrahydrofuran / 16 h / 20 °C / Inert atmosphere 3.1: toluene-4-sulfonic acid / acetonitrile / 10 - 15 °C / Inert atmosphere 3.2: 1.17 h / 20 °C / Inert atmosphere 4.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.17 h / 0 °C / Inert atmosphere 4.2: 0.5 h / Inert atmosphere 5.1: tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene / toluene / 0.08 h / 20 °C / Inert atmosphere 5.2: 16 h / 110 °C / Inert atmosphere 6.1: potassium tert-butylate / dimethyl sulfoxide / 0.17 h / 20 °C / Inert atmosphere View Scheme

1: 75 percent / aq. NH3 / 8 h / Heating 2: N2H4*H2O / Raney-nickel / ethanol / Heating View Scheme

palladium 10 on activated carbon; sodium carbonate; triphenylphosphine in ethylene glycol dimethyl ether T=80°C; Suzuki coupling; 16 h; Inert atmosphere;