二甲基(1-甲基-1H-吲哚-2-基)硅烷醇合成路线 (共 3 条)
反应条件
1: iodobenzene With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; copper(l) iodide; sodium t-butanolate in toluene 0.166667 h; 2: 2-(hydroxydimethylsilyl)-1-methyl-1H-indole in toluene T=20°C; 3 h;
参考文献
Denmark, Scott E.; Baird, John D.; Regens, Christopher S.
Journal of Organic Chemistry, 2008 , vol. 73, # 4 p. 1440 - 1455
反应条件
1: 1-methyl-1H-indole With n-butyllithium in diethyl ether; hexane
5 h; Heating;
2: cyclo-(Me2SiO)3 in diethyl ether; hexane
T=0 - 20°C; 12 h;
参考文献
Denmark, Scott E.; Baird, John D.; Regens, Christopher S.
Journal of Organic Chemistry, 2008 , vol. 73, # 4 p. 1440 - 1455
反应条件
1: para-iodoanisole With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; copper(l) iodide; sodium t-butanolate in toluene
0.166667 h;
2: 2-(hydroxydimethylsilyl)-1-methyl-1H-indole in toluene
T=20°C; 3 h;
参考文献
Denmark, Scott E.; Baird, John D.; Regens, Christopher S.
Journal of Organic Chemistry, 2008 , vol. 73, # 4 p. 1440 - 1455