3-乙烯基-7-氧杂双环[4.1.0]庚-2,4-二烯合成路线 （共 6 条）
反应条件
EtSK in ethanol T=0°C; 1 h;
参考文献
Watabe, Tadashi; Hiratsuka, Akira; Sone, Tomomichi; Ishihama, Tetsuya
Journal of the Chemical Society, Chemical Communications, 1983 , # 10 p. 585 - 586
反应条件
in ethanol T=0°C; 1 h;
参考文献
Watabe, Tadashi; Hiratsuka, Akira; Sone, Tomomichi; Ishihama, Tetsuya
Journal of the Chemical Society, Chemical Communications, 1983 , # 10 p. 585 - 586
反应条件
1: (2R)-2-acetylamino-2-methoxycarbonylethanethiol With sodium hydride in methanol; mineral oil Cooling with iceInert atmosphere; 2: 1-vinylbenzene 3,4-oxide in methanol; mineral oil; pentane 2 h; Inert atmosphere;
参考文献
Linhart, Igor; Mraz, Jaroslav; Scharff, Jan; Krouzelka, Jan; Duskova, Sarka; Nohova, Hana; Vodickova, L'udmila
Chemical Research in Toxicology, 2010 , vol. 23, # 1 p. 251 - 257
反应条件
potassium tert-butylate in diethyl ether
T=-20°C; 0.5 h;
参考文献
Watanabe, Tadashi; Hiratsuka, Akira; Aizawa, Toshiko; Sawahata, Tadashi
Tetrahedron Letters, 1982 , vol. 23, # 11 p. 1185 - 1188
反应条件
1: 1.) Br2, 2.) PBr3 / 1.) CCl4, MeOH 2.) CCl4, 0 deg C
2: perbenzoic acid / CHCl3
3: 75 percent / potassium t-butoxide / diethyl ether / 0.5 h / -20 °C
View Scheme
参考文献
Watanabe, Tadashi; Hiratsuka, Akira; Aizawa, Toshiko; Sawahata, Tadashi
Tetrahedron Letters, 1982 , vol. 23, # 11 p. 1185 - 1188
反应条件
1: perbenzoic acid / CHCl3
2: 75 percent / potassium t-butoxide / diethyl ether / 0.5 h / -20 °C
View Scheme
参考文献
Watanabe, Tadashi; Hiratsuka, Akira; Aizawa, Toshiko; Sawahata, Tadashi
Tetrahedron Letters, 1982 , vol. 23, # 11 p. 1185 - 1188
