叔丁氧基 N-氨基甲酸丙烯合成路线 （共 42 条）
反应条件
1: With n-butyllithium; copper (I) cyanide in tetrahydrofuran T=-78°C; 0.25 h; 2: With tri-n-butyl-tin hydride in tetrahydrofuran T=-78°C; 0.333333 h; 3: prop-2-ynyl-carbamic acid tert-butyl ester in tetrahydrofuran T=-78°C; 1 h;
参考文献
Betschmann, Patrick; Burchat, Andrew F.; Calderwood, David J.; Curtin, Michael L.; Davidsen, Steven K.; Davis, Heather M.; Frey, Robin R.; Heyman, Howard R.; Hirst, Gavin C.; Hrnciar, Peter; Michaelides, Michael R.; Muckey, Melanie A.; Rafferty, Paul; Wada, Carol K.
Patent: US2005/43347 A1, 2005 ;
Location in patent: Page/Page column 67-68 ;
US 20050043347 A1
反应条件
in tetrahydrofuran T=20°C; 4 h;
参考文献
Tayama, Eiji; Sugai, Sayaka
Tetrahedron Letters, 2007 , vol. 48, # 35 p. 6163 - 6166
反应条件
hydrogenchloride in chloroform
参考文献
Takeda Chemical Industries, Ltd.
Patent: EP278621 B1, 1991 ;
参考文献
Shea, Regan G.; Fitzner, Jeffrey N.; Fankhauser, John E.; Spaltenstein, Andreas; Carpino, Philip A.; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5243 - 5252
反应条件
N-chloro-succinimide; N-ethyl-N,N-diisopropylamine in methanol 0 deg C up to r.t.;
参考文献
Shea, Regan G.; Fitzner, Jeffrey N.; Fankhauser, John E.; Spaltenstein, Andreas; Carpino, Philip A.; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5243 - 5252
反应条件
1: sodium hydride 2: trifluoroacetic acid View Scheme
参考文献
Journal of Organic Chemistry, , vol. 79, # 4 p. 1620 - 1625
反应条件
trifluoroacetic acid
参考文献
Journal of Organic Chemistry, , vol. 79, # 4 p. 1620 - 1625
反应条件
O,N-bis-(trifluoroacetyl)-hydroxylamine; hydroxylamine in 1,4-dioxane; water T=100°C; 0.333333 h;
参考文献
Kleinke, Andrew S.; Jamison, Timothy F.
Organic Letters, 2013 , vol. 15, # 3 p. 710 - 713
反应条件
bis(tricyclohexylphosphine)benzylidene ruthenium(IV) dichloride in dichloromethane T=20°C;
参考文献
Canadian Journal of Chemistry, , vol. 79, # 5-6 p. 1049 - 1057
