叔丁氧基 N-氨基甲酸丙烯合成路线 （共 42 条）
反应条件
1: 88.3 percent / m-chloroperoxybenzoic acid / CH2Cl2 / 6 h / Heating 2: 92.2 percent / aq. KOH / 0 - 22 °C 3: 31 percent / pyridinium dichromate / dimethylformamide View Scheme
参考文献
Kawamoto; Wills
Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 16 p. 1916 - 1928
反应条件
1: 3-t-butoxycarbonylamino-1-propene With n-butyllithium in tetrahydrofuran T=-78 - 0°C; 0.25 h; Inert atmosphere; 2: di-tert-butyl dicarbonate in tetrahydrofuran T=-78 - 20°C; 1 h; Inert atmosphere;
参考文献
Prediger, Patricia; Barbosa, Lais Ferreira; Genisson, Yves; Correia, Carlos Roque Duarte
Journal of Organic Chemistry, 2011 , vol. 76, # 19 p. 7737 - 7749
反应条件
1,3-bis-(diphenylphosphino)propane; sodium acetate; palladium diacetate in ethylene glycol T=120°C; Heck Reaction; 12 h; Inert atmosphere; Reagent/catalystSolvent;
参考文献
Tian, Yulin; Qi, Jianguo; Sun, Chenbin; Yin, Dali; Wang, Xiaojian; Xiao, Qiong
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 42 p. 7262 - 7266
反应条件
1,3-bis-(diphenylphosphino)propane; sodium acetate; palladium diacetate in ethylene glycol T=120°C; Heck Reaction; 12 h; Inert atmosphere;
参考文献
Tian, Yulin; Qi, Jianguo; Sun, Chenbin; Yin, Dali; Wang, Xiaojian; Xiao, Qiong
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 42 p. 7262 - 7266
反应条件
1,3-bis-(diphenylphosphino)propane; sodium acetate; palladium diacetate in ethylene glycol T=120°C; Heck Reaction; 12 h; Inert atmosphere;
参考文献
Tian, Yulin; Qi, Jianguo; Sun, Chenbin; Yin, Dali; Wang, Xiaojian; Xiao, Qiong
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 42 p. 7262 - 7266
反应条件
1,4-diaza-bicyclo[2.2.2]octane; 1,1'-bis(diphenylphosphino)ferrocene; palladium diacetate in acetonitrile T=80°C; Heck reaction; 14 h; Inert atmosphere;
参考文献
Baxter, Carl A.; Cleator, Ed; Alam, Mahbub; Davies, Antony J.; Goodyear, Adrian; o'Hagan, Michael
Organic Letters, 2010 , vol. 12, # 4 p. 668 - 671
反应条件
1,1'-bis(diphenylphosphino)ferrocene; N,N-dicyclohexylmethylamine; palladium diacetate in acetonitrile T=80°C; 14 h; Inert atmosphere;
参考文献
Baxter, Carl A.; Cleator, Ed; Alam, Mahbub; Davies, Antony J.; Goodyear, Adrian; o'Hagan, Michael
Organic Letters, 2010 , vol. 12, # 4 p. 668 - 671
反应条件
tert.-butylhydroperoxide; silver hexafluoroantimonate; [Pd(Quinox)Cl2] in dichloromethane; water T=0 - 20°C; 2.5 h; Darkness;
参考文献
Michel, Brian W.; McCombs, Jessica R.; Winkler, Andrea; Sigman, Matthew S.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 40 p. 7312 - 7315
反应条件
KH in propargyl bromide; N,N-dimethyl-formamide
参考文献
Pfizer Inc
Patent: US6156752 A1, 2000 ;
US 6156752 A
反应条件
Ni(PPh3)4 in methanol T=60°C; 120 h; Inert atmosphereSchlenk technique; Overall yield = 94 percent;
参考文献
Wang, Lu; Liu, Chao; Bai, Ruopeng; Pan, Yani; Lei, Aiwen
Chemical Communications, 2013 , vol. 49, # 72 p. 7923 - 7925
