叔丁氧基 N-氨基甲酸丙烯合成路线 （共 42 条）
反应条件
1,1'-bis(diphenylphosphino)ferrocene; sodium acetate; palladium diacetate in acetonitrile T=80°C; Heck reaction; 14 h; Inert atmosphere;
参考文献
Baxter, Carl A.; Cleator, Ed; Alam, Mahbub; Davies, Antony J.; Goodyear, Adrian; o'Hagan, Michael
Organic Letters, 2010 , vol. 12, # 4 p. 668 - 671
反应条件
1,1'-bis(diphenylphosphino)ferrocene; N,N-dicyclohexylmethylamine; palladium diacetate in acetonitrile T=80°C; 14 h; Inert atmosphere;
参考文献
Baxter, Carl A.; Cleator, Ed; Alam, Mahbub; Davies, Antony J.; Goodyear, Adrian; o'Hagan, Michael
Organic Letters, 2010 , vol. 12, # 4 p. 668 - 671
反应条件
1: 50 percent / NaH / tetrahydrofuran / Ambient temperature
2: (-)-sparteine, n-BuLi / diethyl ether; cyclohexane / 2.5 h / -78 °C
View Scheme
参考文献
Serino; Stehle; Yong Sun Park; Florio; Beak
Journal of Organic Chemistry, 1999 , vol. 64, # 4 p. 1160 - 1165
反应条件
dicyclohexylboron chloride; rutheniu carbene in toluene
T=80°C; 12 h;
参考文献
Vedrenne, Emeline; Dupont, Herve; Oualef, Sabrina; Elkaim, Laurent; Grimaud, Laurence
Synlett, 2005 , # 4 art. no. D34504ST, p. 670 - 672
反应条件
1,1'-bis(diphenylphosphino)ferrocene; palladium diacetate; potassium carbonate in acetonitrile
T=80°C; Inert atmosphere;
参考文献
Baxter, Carl A.; Cleator, Ed; Alam, Mahbub; Davies, Antony J.; Goodyear, Adrian; o'Hagan, Michael
Organic Letters, 2010 , vol. 12, # 4 p. 668 - 671
反应条件
sodium acetate; palladium diacetate in ethylene glycol
T=120°C; Heck Reaction; 12 h; Inert atmosphere;
参考文献
Tian, Yulin; Qi, Jianguo; Sun, Chenbin; Yin, Dali; Wang, Xiaojian; Xiao, Qiong
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 42 p. 7262 - 7266
反应条件
[Rh(acac)2(CO)2]; C50H44Cl4N4O4P2; hydrogen in toluene
T=60°C; P=15001.5 Torr; 20 h; Inert atmosphereAutoclave; enantioselective reaction;
参考文献
Xu, Kun; Zheng, Xin; Wang, Zhiyong; Zhang, Xumu
Chemistry - A European Journal, 2014 , vol. 20, # 15 p. 4357 - 4362
反应条件
hydrogen; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; [rhodium(I)(carbonyl)2(acetylacetonate)] in tetrahydrofuran
T=70°C; P=15001.2 Torr; 20 h;
参考文献
Schmidt, Axel M.; Eilbracht, Peter
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 12 p. 2333 - 2343
反应条件
dicarbonylacetylacetonato rhodium (I); hydrogen; (R,S)-Binaphos in toluene
T=60°C; P=15001.5 Torr; 20 h; optical yield given as percent eeenantioselective reaction;
参考文献
Zhang, Xiaowei; Cao, Bonan; Yu, Shichao; Zhang, Xumu
Angewandte Chemie - International Edition, 2010 , vol. 49, # 24 p. 4047 - 4050
反应条件
(3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-(2'-diphenylphosphanyl-[1,1']binaphthalenyl-2-yl)-ethyl-amine; dicarbonylacetylacetonato rhodium (I); hydrogen in toluene
T=60°C; P=7500.75 Torr; 20 h; optical yield given as percent eeenantioselective reaction;
参考文献
Zhang, Xiaowei; Cao, Bonan; Yu, Shichao; Zhang, Xumu
Angewandte Chemie - International Edition, 2010 , vol. 49, # 24 p. 4047 - 4050
