叔丁基二甲基甲硅烷基缩水甘油醚合成路线 （共 8 条）
反应条件
sodium hydride 1.) THF, 10 min, 2.) THF; Yield given. Multistep reaction;
参考文献
Lai, Ming-tain; Oh, Eugene; Shih, Younan; Liu, Hung-wen
Journal of Organic Chemistry, 1992 , vol. 57, # 8 p. 2471 - 2476
反应条件
1H-imidazole in tetrahydrofuran
T=20°C; Inert atmosphere;
参考文献
Loebermann, Florian; Weisheit, Lara; Trauner, Dirk
Organic Letters, 2013 , vol. 15, # 17 p. 4324 - 4326
反应条件
sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid in dichloromethane
Ambient temperature;
参考文献
Lygo, Barry; O'connor, Norval; Wilson, Peter R.
Tetrahedron, 1988 , vol. 44, # 22 p. 6881 - 6888
参考文献
Merck Frosst Canada, Inc.
Patent: US5252599 A1, 1993 ;
反应条件
1: 5.7 g / imidazole / dimethylformamide / 16 h / Ambient temperature
2: 73 percent / m-chloroperoxybenzoic acid, NaHCO3 / CH2Cl2 / Ambient temperature
View Scheme
参考文献
Lygo, Barry; O'connor, Norval; Wilson, Peter R.
Tetrahedron, 1988 , vol. 44, # 22 p. 6881 - 6888
反应条件
potassium carbonate in methanol
参考文献
Kalow, Julia A.; Doyle, Abigail G.
Journal of the American Chemical Society, 2011 , vol. 133, # 40 p. 16001 - 16012
反应条件
1: copper(l) iodide / tetrahydrofuran; diethyl ether / 2.5 h / -40 - 20 °C
2: 1H-imidazole; 4-(N,N-dimethlyamino)pyridine / dichloromethane / 16 h / 20 °C
3: sodium carbonate; ozone; triphenylphosphine / dichloromethane / 3 h / -78 - 20 °C
View Scheme
参考文献
Florence, Gordon J.; Morris, Joanne C.; Murray, Ross G.; Vanga, Raghava R.; Osler, Jonathan D.; Smith, Terry K.
Chemistry - A European Journal, 2013 , vol. 19, # 25 p. 8309 - 8320
反应条件
sodium hydride
1.) THF, 10 min, 2.) THF; Yield given. Multistep reaction;
参考文献
Lai, Ming-tain; Oh, Eugene; Shih, Younan; Liu, Hung-wen
Journal of Organic Chemistry, 1992 , vol. 57, # 8 p. 2471 - 2476
