1,11-二异氰酸-十一烷合成路线 （共 10 条）
反应条件
1: With sodium azide in acetone
T=0 - 20°C; 4 h;
2: in acetone; toluene
T=65°C;
参考文献
Moreau, Joel J. E.; Vellutini, Luc; Man, Michel Wong Chi; Bied, Catherine; Dieudonne, Philippe; Bantignies, Jean-Louis; Sauvajol, Jean-Louis
Chemistry - A European Journal, 2005 , vol. 11, # 5 p. 1527 - 1537
反应条件
triethylamine in chloroform
96 h; Ambient temperature; Yield given;
参考文献
Richter, R.; Tucker, B.; Ulrich, H.
Journal of Organic Chemistry, 1981 , vol. 46, p. 5226 - 5228
反应条件
1.1: 90 percent / thionyl chloride / CH2Cl2 / Heating
2.1: NaN3 / acetone / 4 h / 0 - 20 °C
2.2: 73 percent / acetone; toluene / 65 °C
View Scheme
参考文献
Moreau, Joel J. E.; Vellutini, Luc; Man, Michel Wong Chi; Bied, Catherine; Dieudonne, Philippe; Bantignies, Jean-Louis; Sauvajol, Jean-Louis
Chemistry - A European Journal, 2005 , vol. 11, # 5 p. 1527 - 1537
反应条件
1: H2O / acetone / 20 h
2: Et3N / CHCl3 / 96 h / Ambient temperature
View Scheme
参考文献
Richter, R.; Tucker, B.; Ulrich, H.
Journal of Organic Chemistry, 1981 , vol. 46, p. 5226 - 5228
反应条件
1: CH2Cl2 / 0 °C
2: H2O / acetone / 20 h
3: Et3N / CHCl3 / 96 h / Ambient temperature
View Scheme
参考文献
Richter, R.; Tucker, B.; Ulrich, H.
Journal of Organic Chemistry, 1981 , vol. 46, p. 5226 - 5228
反应条件
1,2-dichloro-benzene
T=160 - 180°C;
参考文献
Siefken
Justus Liebigs Annalen der Chemie, 1949 , vol. 562, p. 75,1114
反应条件
hydrogenchloride; sodium nitrite
Erwaermen des Reaktionsprodukts in Benzol;
参考文献
Iwakura et al.
Nippon Kagaku Zasshi, 1957 , vol. 78, p. 1504
Chem.Abstr., 1960 , p. 1540
反应条件
1: hydrogen chloride; ethanol
2: sodium; methanol / 45 °C / Electrolysis
3: ethanol; hydrazine hydrate
4: aqueous hydrochloric acid; sodium nitrite / Erwaermen des Reaktionsprodukts in Benzol
View Scheme
参考文献
Iwakura et al.
Nippon Kagaku Zasshi, 1957 , vol. 78, p. 1504
Chem.Abstr., 1960 , p. 1540
反应条件
1: sodium; methanol / 45 °C / Electrolysis
2: ethanol; hydrazine hydrate
3: aqueous hydrochloric acid; sodium nitrite / Erwaermen des Reaktionsprodukts in Benzol
View Scheme
参考文献
Iwakura et al.
Nippon Kagaku Zasshi, 1957 , vol. 78, p. 1504
Chem.Abstr., 1960 , p. 1540
反应条件
1: ethanol; hydrazine hydrate
2: aqueous hydrochloric acid; sodium nitrite / Erwaermen des Reaktionsprodukts in Benzol
View Scheme
参考文献
Iwakura et al.
Nippon Kagaku Zasshi, 1957 , vol. 78, p. 1504
Chem.Abstr., 1960 , p. 1540
