water in acetonitrile T=70°C; hydrolytic decomposition in acidic and neutral buffers; pH-dependence of the rate of decomposition; solvent deuterium isotope effect (kH2O/kD2O);; Rate constantMechanismProduct distribution;
参考文献
Journal of Organic Chemistry, , vol. 57, # 2 p. 654 - 661
T=480 - 600°C; P=0.8 - 2.4 Torr; intrinsic gas phase acidity (acid dissociation energy) is measured as a model for strong interactions in proteins and enzymes; Thermodynamic dataKinetics;
参考文献
Journal of the American Chemical Society, , vol. 110, # 10 p. 3071 - 3075
T=-173.1 - 396.9°C; P=0.8 - 2.4 Torr; intrinsic gas phase acidity (acid dissociation energy) is measured as a model for strong interactions in proteins and enzymes; Thermodynamic data;
参考文献
Journal of the American Chemical Society, , vol. 110, # 10 p. 3071 - 3075
