in benzene-d6 EtNO2 added to soln. of n-Bu3SnNMe2 in C6D6 at room temp. under N2, react. mixt. kept at room temp. for 4-48 h; not isolated, detected by NMR;
参考文献
Guibe-Jampel, Eryka; Huet, Francois
Journal of Organometallic Chemistry, 1987 , vol. 320, p. 171 - 176
in tetrahydrofuran T=-70°C; other quenching conditions (replacing of aq. NH4Cl by various proton sources); other Grignard reagent, other nitroalkanes; Product distribution;
参考文献
Bartoli, Giuseppe; Marcantoni, Enrico; Petrini, Marino
Journal of Organic Chemistry, 1992 , vol. 57, # 22 p. 5834 - 5840
phenyl isocyanate; triethylamine in benzene 1.) RT, 42 h, 2.) reflux, 4 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
1: With Hevea brasiliensis hydroxynitrile lyase in phosphate buffer T=20°C; Henry reaction; pH=7; 48 h; 2: With hydrogen; palladium on activated charcoal in ethanol T=20°C; 6 h; Title compound not separated from byproducts;
