aluminium trichloride in dichloromethane T=20°C; 1 h;
参考文献
Bolestova, G. I.; Parnes, Z. N.; Latypova, F. M.; Kursanov, D. N.
Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, # 7 p. 1203 - 1208
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 7 p. 1357 - 1363
Glozshtein, A. Ya.; Sidorov, V. A.; Polyakov, S. A.; Gladysheva, T. V.
J. Appl. Chem. USSR (Engl. Transl.), 1981 , vol. 54, # 5 p. 1145 - 1147,936 - 938
Glozshtein, A. Ya.; Sidorov, V. A.; Polyakov, S. A.; Gladysheva, T. V.
J. Appl. Chem. USSR (Engl. Transl.), 1981 , vol. 54, # 5 p. 1145 - 1147,936 - 938
in toluene A pressure vessel is filled with a soln. of (C5Me5)Hf(C6H10)Cl in toluene and charged with 10 atm of H2, reaction mixture is stirred overnight at 70°C under N2.; Excess H2 is released, hot soln. is transferred into a Schlenk vessel, cooling of the soln. to room temp., a bright yellow ppt. is formed, solvent is decanted, ppt. is redissolved (hot toluene), slow cooling to -30°C, elem. anal.;
参考文献
Booij, Martin; Blenkers, Joop; Sinnema, Jacobus C. M.; Meetsma, Auke; Bolhuis, Fre van; Teuben, Jan H.
Organometallics, 1988 , vol. 7, p. 1029 - 1032
