[Pd{C6H4(CH2N(CH2Ph)2)}(μ-Br)]2; potassium carbonate in N,N-dimethyl-formamide T=100°C; Stille coupling; 0.116667 h; Microwave irradiation;

[Pd{C6H4(CH2N(CH2Ph)2)}(μ-Br)]2; potassium carbonate in N,N-dimethyl-formamide T=100°C; Stille coupling; 0.0833333 h; Microwave irradiation;

tetrakis(triphenylphosphine) palladium(0) in toluene byproducts: (p-CH3COC6H4)2, Bu3SnBr; at 115°C for 15 h in sealed thick wall Pyrex glass ampoules;

trifluoroacetic acid; cobalt(II) dibromide; zinc in acetonitrile CoBr2 and Zn dust activated with CF3CO2H reacted for 5 min with allyl chloride in MeCN, aryl halide and tributylstannyl chloride added simultaneously in MeCN at room temp., stirred for 2 h at 50°C;

tetrakis(triphenylphosphine) palladium(0) in toluene byproducts: (C4H9)3SnI; soln. of Bu3SnSnBu3, Pd(PPh3)4, aryl iodide in toluene heated to 60°C for 72 h under Ar; evapd., washed with aq. KF, extd. (C6H6), dried over Na2SO4, chromd. (SiO2, hexane); elem. anal.;