1: With potassium carbonate; trans-1,2diaminocyclohexane in 1,4-dioxane T=125°C; 0.0833333 h; Heating / reflux; 2: With copper(l) iodide in 1,4-dioxane T=125°C; Heating / reflux;

1: 2-Chlorophenyl-dihydroxyborane; 2-propenamide With potassium phosphate; [RhCl(η2:η2-cycloocta-1,5-diene)]2; bis(η3-allyl-μ-chloropalladium(II)); 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in methanol; 1,1-dimethylpropan-1-ol T=110°C; 16 h; Inert atmosphereSealed tube; 2: 1-(iodo)-4-methylbenzene With potassium phosphate; copper(l) iodide; (1R,2R)-(-)-trans-1,2-diaminocyclohexane in methanol; 1,1-dimethylpropan-1-ol T=20 - 130°C; 16.17 h; Inert atmosphereSealed tubeMolecular sieve;