[氯(苯基硫基)甲基](三甲基)硅烷合成路线 （共 10 条）
反应条件
1: 86 percent / ZnBr2 / CH2Cl2 / 20 h / Ambient temperature; reaction with other silyl enol ethers; synthetic reactions of chloro(phenylthio)methyltrimethylsilane 2: 1.) LDA, 2.) MeI / 1.) hexane, THF, 2 h, 2.) overnight View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 3 p. 435 - 438
反应条件
1: 84 percent 2: NaBH4 / ethanol View Scheme
参考文献
Ager, David J.
Tetrahedron Letters, 1983 , vol. 24, # 4 p. 419 - 422
反应条件
1: lt;chloro(phenylthio)methylgt;trimethylsilane With n-butyllithium in diethyl ether; Petroleum ether T=-78°C; 2: styrene in diethyl ether; Petroleum ether T=20°C; 12 h;
参考文献
European Journal of Organic Chemistry, , # 30 p. 5198 - 5207
反应条件
1: lt;chloro(phenylthio)methylgt;trimethylsilane With n-butyllithium in diethyl ether; Petroleum ether T=-78°C; 2: maleic acid diethyl ester in diethyl ether; Petroleum ether T=20°C; 12 h;
参考文献
European Journal of Organic Chemistry, , # 30 p. 5198 - 5207
反应条件
1: lt;chloro(phenylthio)methylgt;trimethylsilane With n-butyllithium in diethyl ether; Petroleum ether T=-78°C; 2: cyclohexene in diethyl ether; Petroleum ether T=20°C; 12 h;
参考文献
European Journal of Organic Chemistry, , # 30 p. 5198 - 5207
反应条件
nickel
Yield given. Multistep reaction;
参考文献
Fleming, Ian
Bulletin de la Societe Chimique de France, 1981 , vol. 2, # 1-2 p. 7 - 13
反应条件
1: lt;chloro(phenylthio)methylgt;trimethylsilane With n-butyllithium in diethyl ether; Petroleum ether
T=-78°C;
2: styrene in diethyl ether; Petroleum ether
T=20°C; 12 h;
参考文献
Wagner, Tobias; Lange, Jens; Grote, Dirk; Sander, Wolfram; Schaumann, Ernst; Adiwidjaja, Gunadi; Adam, Arnold; Kopf, Juergen
European Journal of Organic Chemistry, 2009 , # 30 p. 5198 - 5207
反应条件
1: lt;chloro(phenylthio)methylgt;trimethylsilane With n-butyllithium in diethyl ether; Petroleum ether
T=-78°C;
2: fumaric acid diethyl ester in diethyl ether; Petroleum ether
T=20°C; 12 h;
参考文献
Wagner, Tobias; Lange, Jens; Grote, Dirk; Sander, Wolfram; Schaumann, Ernst; Adiwidjaja, Gunadi; Adam, Arnold; Kopf, Juergen
European Journal of Organic Chemistry, 2009 , # 30 p. 5198 - 5207
反应条件
1: lt;chloro(phenylthio)methylgt;trimethylsilane With n-butyllithium in diethyl ether; Petroleum ether
T=-78°C;
2: maleic acid diethyl ester in diethyl ether; Petroleum ether
T=20°C; 12 h;
参考文献
Wagner, Tobias; Lange, Jens; Grote, Dirk; Sander, Wolfram; Schaumann, Ernst; Adiwidjaja, Gunadi; Adam, Arnold; Kopf, Juergen
European Journal of Organic Chemistry, 2009 , # 30 p. 5198 - 5207
反应条件
1: lt;chloro(phenylthio)methylgt;trimethylsilane With n-butyllithium in diethyl ether; Petroleum ether
T=-78°C;
2: cyclohexene in diethyl ether; Petroleum ether
T=20°C; 12 h;
参考文献
Wagner, Tobias; Lange, Jens; Grote, Dirk; Sander, Wolfram; Schaumann, Ernst; Adiwidjaja, Gunadi; Adam, Arnold; Kopf, Juergen
European Journal of Organic Chemistry, 2009 , # 30 p. 5198 - 5207
