3,6-二溴-9-正辛基咔唑合成路线 （共 7 条）
反应条件
N-bromosuccinmide in chloroform
T=40°C; 8 h; Inert atmosphere;
参考文献
Zhang, Tianfu; Wang, Jinze; Zhou, Manxi; Ma, Li; Yin, Guangzhong; Chen, Guangxin; Li, Qifang
Tetrahedron, 2014 , vol. 70, # 14 p. 2478 - 2486
反应条件
tetrabutylammomium bromide; sodium hydroxide in toluene
T=120°C;
参考文献
Ren, Ming-Guang; Guo, Hui-Jun; Qi, Fei; Song, Qin-Hua
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 20 p. 6913 - 6916
反应条件
1: 94 percent / benzyltriethylammonium chloride; aq. NaOH / toluene / 16 h / Heating
2: 78 percent / N-bromosuccinimide / tetrahydrofuran / 0 - 20 °C
View Scheme
参考文献
Brunner, Klemens; Van Dijken, Addy; Boerner, Herbert; Bastiaansen, Jolanda J. A. M.; Kiggen, Nicole M. M.; Langeveld, Bea M. W.
Journal of the American Chemical Society, 2004 , vol. 126, # 19 p. 6035 - 6042
反应条件
1: 94 percent / benzyltriethylammonium chloride; aq. NaOH / toluene / 16 h / Heating
2: 78 percent / N-bromosuccinimide / tetrahydrofuran / 0 - 20 °C
View Scheme
参考文献
Brunner, Klemens; Van Dijken, Addy; Boerner, Herbert; Bastiaansen, Jolanda J. A. M.; Kiggen, Nicole M. M.; Langeveld, Bea M. W.
Journal of the American Chemical Society, 2004 , vol. 126, # 19 p. 6035 - 6042
反应条件
1: potassium hydroxide; tetrabutylammomium bromide / toluene
2: N-bromosuccinmide / N,N-dimethyl-formamide
View Scheme
参考文献
Lei, Yanli; Mi, Hongyu; Nurulla, Ismayil; Shi, Wei; Niu, Qiaoli; Wang, Yongli
Dyes and Pigments, 2013 , vol. 96, # 1 p. 138 - 147,10
反应条件
1: 3,6-dibromo-9-octyl-9H-carbazole With sec.-butyllithium in tetrahydrofuran; hexane
T=-78°C; 0.333333 h; Inert atmosphere;
2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran; hexane
T=-78°C; 24 h; Inert atmosphere;
参考文献
Idzik, Krzysztof Ryszard; Cywinski, Piotr J.; Cranfield, Charles G.; Mohr, Gerhard J.; Beckert, Rainer
Journal of Fluorescence, 2011 , vol. 21, # 3 p. 1195 - 1204
反应条件
bis-triphenylphosphine-palladium(II) chloride; potassium acetate in toluene
T=110°C; Miyaura Borylation Reaction; 18 h; Inert atmosphere;
参考文献
Zhang, Ling; Zeng, Shaohang; Yin, Lunxiang; Ji, Changyan; Li, Kechang; Li, Yanqin; Wang, Yue
New Journal of Chemistry, 2013 , vol. 37, # 3 p. 632 - 639
