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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
79602-52-1
合成路线
(共 8 条)
67-56-1
甲醇
+
79602-52-1
→
反应条件
82299-64-7
3,4-二氢-2H-1,4-苯并噻嗪1,1-二氧化物
+
79-20-9
乙酸甲酯
反应条件
sodium methylate Ambient temperatureother bases, other solvents; Rate constant;
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1981 , vol. 18, p. 857 - 859
6397-16-6
→
反应条件
79602-52-1
反应条件
MOA; dihydrogen peroxide in methanol; water Ambient temperatureovernight;
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
137-07-5
2-氨基苯硫醇
→
反应条件
79602-52-1
反应条件
1: 84 percent / sodium methoxide / methanol / 3 h / Heating 2: 66 percent / 3 h / Heating 3: 81 percent / potassium t-butoxide / 2-methyl-propan-2-ol / 0.25 h / 45 °C 4: 79 percent / ammonium molybdate, 30percent hydrogen peroxide / methanol; H2O / Ambient temperature; overnight View Scheme
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
3080-99-7
3,4-二氢-2H-1,4-苯并噻嗪
→
反应条件
79602-52-1
反应条件
1: 84 percent / pyridine / -10 °C 2: 79 percent / ammonium molybdate, 30percent hydrogen peroxide / methanol; H2O / Ambient temperature; overnight View Scheme
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
82595-41-3
→
反应条件
79602-52-1
反应条件
1: 66 percent / 3 h / Heating 2: 81 percent / potassium t-butoxide / 2-methyl-propan-2-ol / 0.25 h / 45 °C 3: 79 percent / ammonium molybdate, 30percent hydrogen peroxide / methanol; H2O / Ambient temperature; overnight View Scheme
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
82595-42-4
→
反应条件
79602-52-1
反应条件
1: 81 percent / potassium t-butoxide / 2-methyl-propan-2-ol / 0.25 h / 45 °C 2: 79 percent / ammonium molybdate, 30percent hydrogen peroxide / methanol; H2O / Ambient temperature; overnight View Scheme
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
79602-52-1
→
反应条件
82299-64-7
3,4-二氢-2H-1,4-苯并噻嗪1,1-二氧化物
反应条件
sodium methylate in methanol T=25°C; 0.166667 h;
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
67-56-1
甲醇
+
79602-52-1
→
反应条件
82299-64-7
3,4-二氢-2H-1,4-苯并噻嗪1,1-二氧化物
+
79-20-9
乙酸甲酯
反应条件
sodium methylate Ambient temperatureother bases, other solvents; Rate constant;
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1981 , vol. 18, p. 857 - 859