3,3-二苯基己基甲基三硅氧烷合成路线 （共 22 条）
参考文献
Gen. Electric Co. Ltd.
Patent: US2469890 , 1946 ;
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Gen. Electric Co. Ltd.
Patent: US2469888 , 1942 ;
反应条件
bis-trimethylsilyl ether; CDD; dimethyl sulfoxide
Irradiation;
参考文献
Swaim,R.E.; Weber,W.P.
Journal of the American Chemical Society, 1979 , vol. 101, p. 5703 - 5706
反应条件
lithium in tetrahydrofuran
T=-78°C; Substitution; 3 h; Further byproducts given;
参考文献
Harloff, Joerg; Popowski, Eckhard; Fuhrmann, Hans
Journal of Organometallic Chemistry, 1999 , vol. 592, # 1 p. 136 - 146
参考文献
Rebrov; Muzafarov
Heteroatom Chemistry, 2006 , vol. 17, # 6 p. 514 - 541
反应条件
1: 50 percent / pentane; diethyl ether / -78 °C
2: Li / tetrahydrofuran / 3 h / -78 °C
View Scheme
参考文献
Harloff, Joerg; Popowski, Eckhard; Fuhrmann, Hans
Journal of Organometallic Chemistry, 1999 , vol. 592, # 1 p. 136 - 146
反应条件
1: KOH / ethanol
2: H2SO4 / not given
View Scheme
参考文献
Gmelin Handbook: Si: MVol.C, 106, page 292 - 295
反应条件
1: HCl / acetone; chloroform
2: KOH / ethanol
3: H2SO4 / not given
View Scheme
参考文献
Gmelin Handbook: Si: MVol.C, 106, page 292 - 295
反应条件
1: 98 percent / sodium tert-isoamylate / diethyl ether; pyridine / 1.5 h / -10 - 25 °C
2: 100 percent / toluene
View Scheme
参考文献
Rebrov; Muzafarov
Heteroatom Chemistry, 2006 , vol. 17, # 6 p. 514 - 541
反应条件
lithium in tetrahydrofuran
T=-78°C; Substitution; addition; 24 h; title comp.:ClSiMe3 ratio 1:10; Product distribution;
参考文献
Harloff, Joerg; Popowski, Eckhard; Fuhrmann, Hans
Journal of Organometallic Chemistry, 1999 , vol. 592, # 1 p. 136 - 146
参考文献
Dow Corning Corp.
Patent: US2611774 , 1950 ;
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Dow Corning Corp.
Patent: US2611774 , 1952 ;
C. A., 1953 , p. 4129
