(9Z,11E)-13-氧代十八碳-9,11-二烯酸甲酯合成路线 （共 5 条）
反应条件
sodium tetrahydroborate; cerium(III) chloride in methanol T=0°C; 0.0833333 h;
参考文献
Iacazio, Gilles
Chemistry and Physics of Lipids, 2003 , vol. 125, # 2 p. 115 - 121
反应条件
trifluoroacetic acid
参考文献
Nagata, Ryu; Morimoto, Shinji; Saito, Isao
Tetrahedron Letters, 1990 , vol. 31, # 31 p. 4485 - 4488
反应条件
1: 70 percent / sodium borohydride / methanol / 0.08 h / 0 °C 2: 100 percent / lithium hydroxide / propan-2-ol; H2O / 1.5 h / Ambient temperature View Scheme
参考文献
Gunn, Bruce P.
Heterocycles, 1985 , vol. 23, # 12 p. 3061 - 3067
反应条件
sodium tetrahydroborate; cerium(III) chloride in methanol
T=0°C; 0.0833333 h;
参考文献
Iacazio, Gilles
Chemistry and Physics of Lipids, 2003 , vol. 125, # 2 p. 115 - 121
反应条件
1: 1.) Co(tdcpp), O2, Et3SiH, 2.) trimethyl phosphite / 1.) i-PrOH, CH2Cl2, 1 atm, 28 deg C, 1 h, 2.) room temperature, 1 h
2: p-TsOH*H2O / benzene / 1 h / Heating
3: 94 percent / 2M NaOH / H2O; methanol / 1 h / Heating
View Scheme
参考文献
Hayashi, Yoshiki; Nishikawa, Yasushi; Mori, Hirotaka; Matsushita, Yoh-ichi; Sugamoto, Kazuhiro; Matsui, Takanao
Bioscience, Biotechnology, and Biochemistry, 1998 , vol. 62, # 9 p. 1771 - 1773
