N-二异丙基-2-溴苯甲酰胺合成路线 （共 5 条）
反应条件
hydrogenchloride; zinc(II) chloride T=160°C; 72 h;
参考文献
Dong, Chang-Zhi; Julia, Marc; Tang, Jie
European Journal of Organic Chemistry, 1998 , # 8 p. 1689 - 1696
反应条件
N-ethyl-N,N-diisopropylamine in diethyl ether
T=0 - 20°C; Schlenk technique;
参考文献
Wertjes, William C.; Wolfe, Lydia C.; Waller, Peter J.; Kalyani, Dipannita
Organic Letters, 2013 , vol. 15, # 23 p. 5986 - 5989
反应条件
N-bromosuccinmide; silver hexafluoroantimonate; [(η5-C5Me5)2Rh2(μ-Cl)2Cl2]; 2,2,2-trimethylacetic acid in 1,2-dichloro-ethane
T=60°C; 16 h; Inert atmosphere; Kinetics; regioselective reaction;
参考文献
Schroeder, Nils; Wencel-Delord, Joanna; Glorius, Frank
Journal of the American Chemical Society, 2012 , vol. 134, # 20 p. 8298 - 8301
反应条件
1: triethylamine / dichloromethane / 20 °C / Inert atmosphere
2: N-bromosuccinmide; silver hexafluoroantimonate; [(η5-C5Me5)2Rh2(μ-Cl)2Cl2]; 2,2,2-trimethylacetic acid / 1,2-dichloro-ethane / 16 h / 60 °C / Inert atmosphere
View Scheme
参考文献
Schroeder, Nils; Wencel-Delord, Joanna; Glorius, Frank
Journal of the American Chemical Society, 2012 , vol. 134, # 20 p. 8298 - 8301
反应条件
1: triethylamine / dichloromethane / 20 °C / Inert atmosphere
2: N-bromosuccinmide; silver hexafluoroantimonate; [(η5-C5Me5)2Rh2(μ-Cl)2Cl2]; 2,2,2-trimethylacetic acid / 1,2-dichloro-ethane / 16 h / 60 °C / Inert atmosphere
View Scheme
参考文献
Schroeder, Nils; Wencel-Delord, Joanna; Glorius, Frank
Journal of the American Chemical Society, 2012 , vol. 134, # 20 p. 8298 - 8301
