Defucogilvocarcin V合成路线 （共 43 条）
反应条件
1: 1.) potassium carbonate; 2.) pyridine, dimethylaminopyridine / 1.) DMSO, acetone, r.t., 2 h
2: 75 percent / N-bromosuccinimide, dibenzoylperoxide / CCl4 / 6 h / Heating
3: 1.) sodium borohydride, diphenyl diselenide; 2.) 30percent H2O2 / 1.) ethanol, THF, 2.5 h, reflux; 2.) THF, ethanol, 3 h, 0 deg C
View Scheme
参考文献
Findlay, John A.; Daljeet, Anand; Murray, Peter John; Rej, Rabindra N.
Canadian Journal of Chemistry, 1987 , vol. 65, p. 427 - 431
反应条件
1: 1.) hydriodic acid; 2.) hydriodic acid / 1.) glacial acetic acid, reflux, 2 h; 2.) acetic acid, reflux, 7 h
2: 1.) potassium carbonate; 2.) pyridine, dimethylaminopyridine / 1.) DMSO, acetone, r.t., 2 h
3: 75 percent / N-bromosuccinimide, dibenzoylperoxide / CCl4 / 6 h / Heating
4: 1.) sodium borohydride, diphenyl diselenide; 2.) 30percent H2O2 / 1.) ethanol, THF, 2.5 h, reflux; 2.) THF, ethanol, 3 h, 0 deg C
View Scheme
参考文献
Findlay, John A.; Daljeet, Anand; Murray, Peter John; Rej, Rabindra N.
Canadian Journal of Chemistry, 1987 , vol. 65, p. 427 - 431
反应条件
in potassium hydroxide; water
6 h; Heating;
参考文献
Findlay; Liu
Canadian Journal of Chemistry, 1983 , vol. 61, # 2 p. 323 - 327
