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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
80221-14-3
合成路线
（共 8 条）
5029-67-4
2-碘吡啶
+
766-97-2
4-甲苯基乙炔
→
反应条件
80221-14-3
反应条件
C10H24Cl2N2Pd2Se2; triethylamine in 1,4-dioxane T=100°C; Sonogashira Cross-Coupling; 12 h; Schlenk technique;
参考文献
Khairnar, Bhikan J.; Dey, Sandip; Jain, Vimal K.; Bhanage, Bhalchandra M.
Tetrahedron Letters, 2014 , vol. 55, # 3 p. 716 - 719
109-04-6
邻溴吡啶
+
766-97-2
4-甲苯基乙炔
→
反应条件
80221-14-3
反应条件
copper(l) iodide; potassium tetrachloropalladate; N,N,N',N,-tetramethylethylenediamine; cataCXium PIntB T=80°C; Sonogashira coupling; 20 h; Inert atmosphere;
参考文献
Prateeptongkum, Saisuree; Driller, Katrin Marie; Jackstell, Ralf; Spannenberg, Anke; Beller, Matthias
Chemistry - A European Journal, 2010 , vol. 16, # 31 p. 9606 - 9615
5142-75-6
三对甲苯基铋
+
182815-94-7
→
反应条件
613-33-2
4,4'-二甲基联苯
+
80221-14-3
反应条件
potassium phosphate; tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide T=90°C; 2 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Jadhav, Deepak N.; Dasgupta, Priyabrata
Organic Letters, 2010 , vol. 12, # 9 p. 2048 - 2051
109-09-1
2-氯吡啶
+
766-97-2
4-甲苯基乙炔
→
反应条件
80221-14-3
反应条件
piperidine; tetrabutylammomium bromide in water T=60°C; Sonogashira coupling; 8 h;
参考文献
Lee, Dong-Hwan; Jung, Ji-Young; Jin, Myung-Jong
Green Chemistry, 2010 , vol. 12, # 11 p. 2024 - 2029
1945-84-2
2-乙炔基吡啶
+
624-31-7
4-碘甲苯
→
反应条件
80221-14-3
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine T=60°C; Sonogashira coupling; 0.0833333 h; Inert atmosphereMicrowave irradiation;
参考文献
Cikova, Martina; Kolivoska, Viliam; Cisarova, Ivana; Saman, David; Pospisil, Lubomir; Teply, Filip
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 2 p. 450 - 462
109-04-6
邻溴吡啶
+
624-31-7
4-碘甲苯
+
471-25-0
丙炔酸
→
反应条件
2789-88-0
1,1'-(1,2-乙炔二基)二(4-甲基苯)
+
80221-14-3
反应条件
bis-triphenylphosphine-palladium(II) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-di(diphenylphosphino)-butane in dimethyl sulfoxide T=50 - 80°C;
参考文献
Park, Kyungho; Bae, Goun; Moon, Jeongju; Choe, Jaehoon; Song, Kwang Ho; Lee, Sunwoo
Journal of Organic Chemistry, 2010 , vol. 75, # 18 p. 6244 - 6251
109-04-6
邻溴吡啶
+
624-31-7
4-碘甲苯
+
1066-54-2
三甲基乙炔基硅
→
反应条件
80221-14-3
反应条件
1: 2-bromo-pyridine; trimethylsilylacetylene With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine; triphenylphosphine in toluene T=25 - 80°C; Sonogashira coupling; 16.0833 h; Inert atmosphere; 2: With water; potassium hydroxide in methanol; toluene T=25°C; 3 h; Inert atmosphere; 3: 1-(iodo)-4-methylbenzene in methanol; water; toluene T=25°C; Sonogashira coupling; 16 h; Inert atmosphere;
参考文献
Severin, Rene; Reimer, Jessica; Doye, Sven
Journal of Organic Chemistry, 2010 , vol. 75, # 10 p. 3518 - 3521
1945-84-2
2-乙炔基吡啶
+
106-38-7
对溴甲苯
→
反应条件
80221-14-3
反应条件
triethylamine in isopropyl alcohol T=100°C; Sonogashira Cross-Coupling; 7 h; Catalytic behavior;
参考文献
UlIslam, Rafique; Mahato, Sanjit K.; Shukla, Sudheesh K.; Witcomb, Michael J.; Mallick, Kaushik
ChemCatChem, 2013 , vol. 5, # 8 p. 2453 - 2461
