n-butyllithium in diethyl ether; hexane
T=-78 - 20°C; 4 h;
参考文献
Cornet, Stephanie M.; Dillon, Keith B.; Entwistle, Christopher D.; Fox, Mark A.; Goeta, Andres E.; Goodwin, Helen P.; Marder, Todd B.; Thompson, Amber L.
Dalton Transactions, 2003 , # 23 p. 4395 - 4405
in diethyl ether; hexane
byproducts: LiCl; (N2); Schlenk technique or glovebox; soln. of mixt. of Li compd. (2 equiv.) in Et2O was added dropwise to soln. of GeCl4 (1 equiv.) in hexane at-78°C; soln. was warmed to room temp. and stirred for 2 h; filtered; solvents removed (vac.); distd. (0.01 Torr, 80-90°C); elem. anal.;
参考文献
Batsanov, Andrei S.; Cornet, Stephanie M.; Dillon, Keith B.; Goeta, Andres E.; Thompson, Amber L.; Xue, Bao Yu
Dalton Transactions, 2003 , # 12 p. 2496 - 2502
in diethyl ether; hexane
byproducts: LiCl; (N2); Schlenk technique or glovebox; soln. of mixt. of Li compd. (2 equiv.) in Et2O was added dropwise to soln. of SnCl4 (1 equiv.) in hexane atroom temp. and stirred for 4 h; filtered; solvents removed (vac.); oily residue filtered; filtered-off residue washed (pentane; CH2Cl2); dried (vac.); recrystd. (pentane and Et2O); elem. anal.;
参考文献
Batsanov, Andrei S.; Cornet, Stephanie M.; Dillon, Keith B.; Goeta, Andres E.; Thompson, Amber L.; Xue, Bao Yu
Dalton Transactions, 2003 , # 12 p. 2496 - 2502
in diethyl ether; hexane
byproducts: LiCl; (N2); Schlenk technique or glovebox; soln. of mixt. of Li compd. (2 equiv.) in Et2O was added dropwise to soln. of SnCl4 (1 equiv.) in hexane atroom temp. and stirred for 4 h; filtered; solvents removed (vac.); oily residue filtered; filtered-off residue washed (pentane; CH2Cl2); dried (vac.); recrystd. (pentane and Et2O); elem. anal.;
参考文献
Batsanov, Andrei S.; Cornet, Stephanie M.; Dillon, Keith B.; Goeta, Andres E.; Thompson, Amber L.; Xue, Bao Yu
Dalton Transactions, 2003 , # 12 p. 2496 - 2502
