三异丙基甲硅烷基三氟甲烷磺酸盐合成路线 （共 52 条）
反应条件
in tetrahydrofuran 5 h; Ambient temperature;
参考文献
Muchowski, Joseph M.; Naef, Reto; Maddox, Michael L.
Tetrahedron Letters, 1985 , vol. 26, # 44 p. 5375 - 5378
反应条件
1: 3-bromo-9-benzyl-9H-carbazole With n-butyllithium in tetrahydrofuran; hexane T=-78 - -74°C; Inert atmosphere; 2: tri-isopropylsylil trifluoromethane sulfonate in tetrahydrofuran; hexane T=-78 - 20°C; Inert atmosphere;
参考文献
SOLVAY SA; MARTIN, Roland; MATHIEU, Veronique; SOROKIN, Victor; BACHAWALA, Praveen; MAZUR, Wieslaw Adam; MAUNOURY, Jonathan
Patent: WO2010/43693 A1, 2010 ;
Location in patent: Page/Page column 20 ;
反应条件
N-ethyl-N,N-diisopropylamine Ambient temperatureovernight;
参考文献
Castan, Florence; Baceiredo, Antoine; Bigg, Dennis; Bertrand, G.
Journal of Organic Chemistry, 1991 , vol. 56, # 5 p. 1801 - 1807
反应条件
1: 1-but-3-ynyl-3,5-dimethyl-benzene With lithium hexamethyldisilazane in tetrahydrofuran
T=-78°C;
2: With tBuOOLi in tetrahydrofuran; toluene
T=-78 - 0°C; 2.5 h;
3: tri-isopropylsylil trifluoromethane sulfonate in tetrahydrofuran; toluene
T=0°C; 0.5 h;
参考文献
Zhang, Liming; Kozmin, Sergey A.
Journal of the American Chemical Society, 2004 , vol. 126, # 33 p. 10204 - 10205
反应条件
1: 4-(2-naphthyl)-1-butyne With lithium hexamethyldisilazane in tetrahydrofuran
T=-78°C;
2: With tBuOOLi in tetrahydrofuran; toluene
T=-78 - 0°C; 2.5 h;
3: tri-isopropylsylil trifluoromethane sulfonate in tetrahydrofuran; toluene
T=0°C; 0.5 h;
参考文献
Zhang, Liming; Sun, Jianwei; Kozmin, Sergey A.
Tetrahedron, 2006 , vol. 62, # 49 p. 11371 - 11380
反应条件
1: (2-propyl-but-3-ynyl)-benzene With lithium hexamethyldisilazane in tetrahydrofuran
T=-78°C;
2: With tBuOOLi in tetrahydrofuran; toluene
T=-78 - 0°C; 2.5 h;
3: tri-isopropylsylil trifluoromethane sulfonate in tetrahydrofuran; toluene
T=-78 - 0°C;
参考文献
Zhang, Liming; Sun, Jianwei; Kozmin, Sergey A.
Tetrahedron, 2006 , vol. 62, # 49 p. 11371 - 11380
反应条件
1: 1-(but-3-yn-1-yl)-3-methoxybenzene With lithium hexamethyldisilazane in tetrahydrofuran
T=-78°C;
2: With tBuOOLi in tetrahydrofuran; toluene
T=-78 - 0°C; 2.5 h;
3: tri-isopropylsylil trifluoromethane sulfonate in tetrahydrofuran; toluene
T=0°C; 0.5 h;
参考文献
Zhang, Liming; Sun, Jianwei; Kozmin, Sergey A.
Tetrahedron, 2006 , vol. 62, # 49 p. 11371 - 11380
反应条件
1: 1-bromo-4-(but-3-yn-1-yl)benzene With lithium hexamethyldisilazane in tetrahydrofuran
T=-78°C;
2: With tBuOOLi in tetrahydrofuran; toluene
T=-78 - 0°C; 2.5 h;
3: tri-isopropylsylil trifluoromethane sulfonate in tetrahydrofuran; toluene
T=0°C; 0.5 h;
参考文献
Zhang, Liming; Sun, Jianwei; Kozmin, Sergey A.
Tetrahedron, 2006 , vol. 62, # 49 p. 11371 - 11380
反应条件
1: 2-methyl-4-propyl-hex-1-en-5-yne With lithium hexamethyldisilazane in tetrahydrofuran
T=-78°C;
2: With tBuOOLi in tetrahydrofuran; toluene
T=-78 - 0°C; 2.5 h;
3: tri-isopropylsylil trifluoromethane sulfonate in tetrahydrofuran; toluene
T=-78 - 0°C;
参考文献
Zhang, Liming; Sun, Jianwei; Kozmin, Sergey A.
Tetrahedron, 2006 , vol. 62, # 49 p. 11371 - 11380
反应条件
1: (1-methylene-3-propyl-pent-4-ynyl)-benzene With lithium hexamethyldisilazane in tetrahydrofuran
T=-78°C;
2: With tBuOOLi in tetrahydrofuran; toluene
T=-78 - 0°C; 2.5 h;
3: tri-isopropylsylil trifluoromethane sulfonate in tetrahydrofuran; toluene
T=-78 - 0°C;
参考文献
Zhang, Liming; Sun, Jianwei; Kozmin, Sergey A.
Tetrahedron, 2006 , vol. 62, # 49 p. 11371 - 11380
