2-(二苯基膦基)-1,3-苯并噻唑合成路线 （共 4 条）
反应条件
1: cyclobenzothiazole With (TMP)2Zn*2MgCl2*2LiCl in tetrahydrofuran
T=25°C; 0.5 h;
2: chloro-diphenylphosphine in tetrahydrofuran
T=25°C; 5 h; Further stages.;
参考文献
Wunderlich, Stefan H.; Knochel, Paul
Angewandte Chemie - International Edition, 2007 , vol. 46, # 40 p. 7685 - 7688
反应条件
benzo[d]thiazol-2-yl halide in tetrahydrofuran
T=20°C; 8 h; Inert atmosphere;
参考文献
Zink, Daniel M.; Baechle, Michael; Baumann, Thomas; Nieger, Martin; Kuehn, Michael; Wang, Cong; Klopper, Wim; Monkowius, Uwe; Hofbeck, Thomas; Yersin, Hartmut; Braese, Stefan
Inorganic Chemistry, 2013 , vol. 52, # 5 p. 2292 - 2305
反应条件
1: lithium / tetrahydrofuran / 0 - 20 °C / |Inert atmosphere
2: benzo[d]thiazol-2-yl halide / tetrahydrofuran / 8 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
Zink, Daniel M.; Baechle, Michael; Baumann, Thomas; Nieger, Martin; Kuehn, Michael; Wang, Cong; Klopper, Wim; Monkowius, Uwe; Hofbeck, Thomas; Yersin, Hartmut; Braese, Stefan
Inorganic Chemistry, 2013 , vol. 52, # 5 p. 2292 - 2305
反应条件
1.) RT, 2 h, 2.) 60 deg C, 30 min, 3.) 100-110 deg C, 10 h;
参考文献
Moore, Stephen S.; Whitesides, George M.
Journal of Organic Chemistry, 1982 , vol. 47, # 8 p. 1489 - 1493
