1,3-二甲基-1,1,3,3-四苯基二硅氧烷合成路线 （共 31 条）
反应条件
potassium tert-butylate in N,N-dimethyl-formamide
参考文献
Inoue, Atsushi; Kondo, Junichi; Shinokubo, Hiroshi; Oshima, Koichiro
Chemistry Letters, 2001 , # 10 p. 956 - 957
反应条件
1: diethyl ether / 12 h / 0 - 20 °C / Inert atmosphere
2: trimethyl-oxonium tetrafluoroborate; potassium carbonate / acetonitrile / 1.5 h / 100 °C / Inert atmosphere
View Scheme
参考文献
Jorapur, Yogesh R.; Shimada, Toyoshi
Synlett, 2012 , vol. 23, # 11 p. 1633 - 1638
反应条件
1: diethyl ether / 12 h / 0 - 20 °C / Inert atmosphere
2: trimethyl-oxonium tetrafluoroborate; potassium carbonate / acetonitrile / 1.5 h / 100 °C / Inert atmosphere
View Scheme
参考文献
Jorapur, Yogesh R.; Shimada, Toyoshi
Synlett, 2012 , vol. 23, # 11 p. 1633 - 1638
参考文献
Mitsudome, Takato; Noujima, Akifumi; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi
Chemical Communications, 2009 , # 35 p. 5302 - 5304
反应条件
1: triethylamine; 4-(N,N-dimethlyamino)pyridine / dichloromethane
2: palladium on activated charcoal; hydrogen / THF-d8 (tetrahydrofuran-d8) / 1.5 h / 20 °C / 760.05 Torr
View Scheme
参考文献
Igarashi, Masayasu; Matsumoto, Tomohiro; Sato, Kazuhiko; Ando, Wataru; Shimada, Shigeru
Chemistry Letters, 2014 , vol. 43, # 4 p. 429 - 431
参考文献
Scheim, U.; Ruehlmann, K.; Kelly, J. W.; Evans, S. A.
Journal of Organometallic Chemistry, 1989 , vol. 375, p. 33 - 38
反应条件
meta-chloroperoxybenzoic acid in benzene
T=45°C; Rate constant;
参考文献
Razuvaev, G. A.; Brevnova, T. N.; Semenov, V. V.; Kornev, A. N.
J. Gen. Chem. USSR (Engl. Transl.), 1986 , vol. 56, # 4 p. 877 - 883,773 - 778
反应条件
in acetonitrile
constant current electrolysis, two-compartment cell, platinum plates as anode and cathode, tetrabutylammonium tetrafluoroborate; Yields of byproduct given;
参考文献
Okano, Mitsutoshi; Mochida, Kunio
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 4 p. 1381 - 1382
反应条件
1: diethyl ether / Erhitzen des Reaktionsprodukts auf ca.120grad
2: petroleum ether; KOH-solution / folgende Destillation
View Scheme
参考文献
Kipping
Journal of the Chemical Society, 1927 , p. 105
反应条件
T=25°C; 1344 h; other temperature, other time; Kinetics;
参考文献
Dubiel, S. V.; Griffith, G. W.; Long, C. L.; Baker, G. K.; Smith, Robert E.
Analytical Chemistry, 1983 , vol. 55, p. 1533 - 1537
